5 out of 138 (3.6%) in one study published in a journal. "Incapacitation by a shot to the head is achieved when the bullet penetrates the cerebrum; however, numerous bullet trajectories, including a shot between the eyes, do not achieve this penetration."[0]
I share the suspicion, but it's apparently likely enough, that you can't immediately conclude it wasn't suicide just because there were two shots.
As someone who survived a couple of bullets to the head over thirty years ago (one penetrating the skull and causing moderate optical cortical brain dameage) I can corroborate this...
Yeah, I agree, its just that Webb wasn't any normal suicide-his exposes on the CIA and their ilk just add a ton of fuel to the fire that you wouldn't have with a run of the mill suicide.
Look at the # of people who survive being shot in the head once, and you may see an answer to your confusion. A person can survive being shot in the head once, and if a person is suicidal the chance that they are lucid enough after the first shot to deliver the second is, often enough it seems, quite high.