I would imagine most large-scale data center construction projects will include electrical engineers to design the electrical subsystem. A rack's floor footprint is a few square feet. You can put several million dollars of hardware into that rack. A data center will have at least a few racks. It's a very reasonable investment to bring someone in to do electrical design.
The goop is generally considered to be unnecessary. What you need is a termination that is rated for aluminum wire, and these are very, very common as long as the wire in question is fairly large (8AWG or so and larger).
I only put it in the comment since the commenters here seemed uninformed.
It's better to be safe and follow specs; it's more when you're doing some compound splice where it makes sense. I figure it'll make more people feel easy about it if there's a preventative measure
Look at the electrical fires of the 1950’s and 1960’s as an example, and that was at household levels of current.
Aluminum is used, but everything accounts for the insane coefficient of linear expansion and other annoying properties.