For several types of certificate and ssl issues(HSTS , blacklisted/revoked certificates) that option is hidden and thus unavailble. Chrome can be a stickler, which is understandable as the majority of its users are not prepared to deal with the possible downsides of going to an untrusted page.
I remember reading some blog post that badly configured SSL certificate will cause something like 90% of people bouncing off the website because they are scared of the big red Chrome warning. SSL certificate is actually an important UX factor.
I think.